Denaturing action of urea and guanidine hydrochloride towards two thermophilic esterases

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Denaturing action of urea and guanidine hydrochloride towards two thermophilic esterases.

The stability of two thermophilic esterases, AFEST from Archaeoglobus fulgidus and EST2 from Alicyclobacillus acidocaldarius, against the denaturing action of urea and guanidine hydrochloride has been investigated by means of steady-state fluorescence and circular dichroism measurements. Experimental results indicate that the two enzymes, even though very resistant to temperature and urea, show...

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Probing Conformational Stability and Dynamics of Erythroid and Nonerythroid Spectrin: Effects of Urea and Guanidine Hydrochloride

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Viscosity and density of aqueous solutions of urea and guanidine hydrochloride.

Densities and viscosities of aqueous solutions of urea and guanidine hydrochloride at 250 have been measured, and equations are presented which describe their variation with concentration. Densities and viscosities of similar solutions containing additional solutes (buffers, NaCI, -mercaptoethanol) have been measured, and the possibility of predicting these results from information on solutions...

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The catalytic activity of several proteolytic enzymes is altered by high concentrations of urea and guanidine salts (2-4). These studies, in conjunction with certain physical data, indicate that hydrogen bonding in the secondary structure of these enzymes is essential for maintenance of their catalytic function. Because of the increasing amount of information that is available concerning the st...

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ژورنال

عنوان ژورنال: Biochemical Journal

سال: 2002

ISSN: 0264-6021,1470-8728

DOI: 10.1042/bj20020695